Oxidation of Cyclohexanone to Adipic Acid with 30% H2O2 and Tungstate Catalyst

Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (3): 319-321. Previous Articles Next Articles

钨化合物催化过氧化氢氧化环己酮合成己二酸

丁宗彪, 连慧, 王全瑞, 陶凤岗^*

复旦大学化学系上海 200433

收稿日期:2003-03-04 修回日期:2003-09-16 接受日期:2003-09-16 发布日期:2022-09-20
基金资助:
国家自然科学基金(No. 29974018)资助项目

Oxidation of Cyclohexanone to Adipic Acid with 30% H₂O₂ and Tungstate Catalyst

DING, Zong-Biao, LIAN, Hui, WANG, Quan-Rui, TAO, Feng-Gang^*

Department of Chemistry, Fudan University, Shanghai 200433

Received:2003-03-04 Revised:2003-09-16 Accepted:2003-09-16 Published:2022-09-20
Contact: *E-mail: szgaoy@163.net

Abstract

Cyclohexanone can be directly oxidized to adipic acid with 30% H₂O₂ using Na₂WO₄·2H₂O or H₇[P-(W₂O₇)₆]·xH₂O as a catalyst without any phase transfer catalyst. The quantity of tungstate catalysts and the acidity of reaction mixture affect the results greatly. It is found that when pH ofthe reaction mixture is 1.0 and 1.5% tungstate catalyst is used, 82% yield ofadipic acid can be obtained. The catalyst can be recycled easily with no loss ofthe activity.

Key words: cyclohexanone, sodium tungstate, phosphotungstic acid, peroxide hydrogen

Cite this article

DING, Zong-Biao, LIAN, Hui, WANG, Quan-Rui, TAO, Feng-Gang. Oxidation of Cyclohexanone to Adipic Acid with 30% H₂O₂ and Tungstate Catalyst[J]. Chinese Journal of Organic Chemistry, 2004, 24(3): 319-321.

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钨化合物催化过氧化氢氧化环己酮合成己二酸

Oxidation of Cyclohexanone to Adipic Acid with 30% H₂O₂ and Tungstate Catalyst

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