Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (1): 29-33. Previous Articles     Next Articles

含茂、非茂混合配体钛族络合物的合成与催化烯烃聚合的研究进展

廉兵, 黄吉玲*, 钱延龙, 陈琦辉   

  1. 华东理工大学金属有机化学研究室 上海 200237
  • 收稿日期:2003-01-10 修回日期:2003-03-19 接受日期:2003-06-03 发布日期:2022-09-21
  • 基金资助:
    国家重大基础研究(No. G1999064801)、国家自然科学基金(No. 20072004)、高等学校博士点专项科研基金和华东理工大学博士学位论文创新行动计划(2003年)资助项目.

Progress in Synthesis of Group 4 Complex with Cp and Non-Cp Mixed Ligands and Their Catalytic Application for α-Olefin Polymerization

LIAN Bing, HUANG Ji-Ling*, QIAN Yan-Long, CHEN Qi-Hui   

  1. Laboratory of Organometallic Chemistry, East China University of Science and Technology, Shanghai 200237
  • Received:2003-01-10 Revised:2003-03-19 Accepted:2003-06-03 Published:2022-09-21
  • Contact: *E-mail: qianling@online.sh.cn

The progresses ofgroup 4 complex exhibit multi-trends: Cp complex, non-Cp complex and complex with Cp and non-Cp mixed ligands. Among them, the complex with Cp and non-Cp mixed ligands is a new shining-point. In recent years, there are many reviews about Cp complex or non-Cp complex, but there is few review regarding the complexwith Cp and non-Cp mixed ligands. This paper reviews the latest progress in thesynthesis of group 4 complexes with Cp and non-Cp mixed ligands and their catalytic application for olefin polymerization.

Key words: Cp and non-Cp mixed ligand, group 4 complex, olefin polymerization