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Synthesis and Characterization of Phosphine-Fuctionalized Biimidazole

  • Guo Miao ,
  • Zhang Tao ,
  • Chen Bo ,
  • Liang Hongze ,
  • Lei Kewei
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  • Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211

Received date: 2011-10-08

  Revised date: 2011-11-09

  Online published: 2012-04-24

Supported by

Project supported by the Natural Science Foundation of Zhejiang Province (No. Y4100113), the Natural Science Foundation of Ningbo City (No. 2010A610027) and the K. C. Wong Magma Found of Ningbo University.

Abstract

Starting from N,N'-biimidazolyl diesters, N,N'-biimidazolyl diphosphine was synthesized by sequent reactions of reduction, chlorination and nucleophilic substitution. It has been characterized by IR, NMR and MS techniques. The two precursors of N,N'-biimidazolyl alcohol and N,N'-biimidazolyl chloride can be further functionalized and thus provide opportunities to synthesize a series of biimidazole derivatives.

Cite this article

Guo Miao , Zhang Tao , Chen Bo , Liang Hongze , Lei Kewei . Synthesis and Characterization of Phosphine-Fuctionalized Biimidazole[J]. Chinese Journal of Organic Chemistry, 2012 , 32(04) : 799 -801 . DOI: 10.6023/cjoc1110082

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