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Chinese Journal of Organic Chemistry >

2012 , Vol. 32 >Issue 04: 709 - 713

DOI: https://doi.org/10.6023/cjoc1110072

Articles

Synthesis, Characterization and Properties of Metallic Magnesium Complexes of meso-Tetrakis(4-alkoxyphenyl)porphyrins

  • Liu Jiepin ,
  • Yang Deliang ,
  • Cao Hua ,
  • Zhao Hongbin
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  • a Medical Technology Institute, Xiangtan Vocational & Technical College, Xiangtan 411103;
    b College of Chemistry, Xiangtan University, Xiangtan 411105;
    c Guangdong Delian Group Co., Ltd, Guangdong 510630

Received date: 2011-10-07

  Revised date: 2011-12-13

  Online published: 2012-04-24

Supported by

Project supported by the Scientific Research Project of Xiangtan of Hunan Province (No. JZ200811) and the Natural Science Foundation of Hunan Province of China (No. 04JJ40013).

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Abstract

A series of magnesium complexes of porphyrins were synthesized. Molecular structures of all synthesized compounds were confirmed by UV-Vis, 1H NMR, IR, MS techniques and elemental analysis. Characteristic spectrometric data of IR, UV-Vis, 1H NMR related to their structures have been systematically analyzed. Differential scanning calorimetry (DSC) and polarizing microscope (PM) were used to probe the liquid crystal properties of the serial complexes. Six of the serial complexes were found to exhibit liquid crystal properties. The effects of alkoxy chains, metal ions of complexes and molecular space structure on liquid crystal properties have been investigated.

Key words： magnesium complexes of porphyrin; synthesis; characterization; liquid crystal property

Cite this article

Liu Jiepin , Yang Deliang , Cao Hua , Zhao Hongbin . Synthesis, Characterization and Properties of Metallic Magnesium Complexes of meso-Tetrakis(4-alkoxyphenyl)porphyrins[J]. Chinese Journal of Organic Chemistry, 2012 , 32(04) : 709 -713 . DOI: 10.6023/cjoc1110072

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