Notes

Solvent-Free Achiral Cyanosilylation of Aldehydes and Ketones Catalyzed by LiNTf2

  • Wang Hongshe ,
  • Zeng June
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  • Shaanxi Key Laboratory for Phytochemistry, Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721013

Received date: 2011-10-24

  Revised date: 2011-12-20

  Online published: 2012-01-11

Supported by

Project supported by the Scientific Research Program of Shaanxi Provincial Education Deparment (No. 09JK332) and the Key Project of Baoji University of Arts and Sciences (No. ZK1053).

Abstract

An efficient method for the addition of trimethylsilyl cyanide (TMSCN) to various aldehydes and ketones has been described using LiNTf2 (1 mol%) as a catalyst at room temperature under solvent-free conditions. The advantages of this method are easy work-up, mild reaction conditions, high yields and the catalyst exhibited remarkable reusable activity.

Cite this article

Wang Hongshe , Zeng June . Solvent-Free Achiral Cyanosilylation of Aldehydes and Ketones Catalyzed by LiNTf2[J]. Chinese Journal of Organic Chemistry, 2012 , 32(05) : 934 -938 . DOI: 10.6023/cjoc1110242

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