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Chinese Journal of Organic Chemistry >

2012 , Vol. 32 >Issue 01: 189 - 192

DOI: https://doi.org/10.6023/cjoc1105292

Notes

One-Pot Syntheses of Calix[4]-bis-crowns and Biscalix[4]crown with Two Kinds of Bridging Chains

  • YE Jin-Qi ,
  • YANG Fa-Fu ,
  • ZHANG Xiao-Yi ,
  • JIAO Zi-Yu ,
  • GUO Hong-Yu
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  • a College of Chemistry and Materials, Fujian Normal University, Fuzhou 350007;
    b Fujian Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou 350007

Received date: 2011-05-29

  Revised date: 2011-08-18

  Online published: 2011-09-05

Supported by

Project supported by the National Natural Science Foundation of China (No. 20402002), the Natural Science Foundation of Fujian Province (No. 2011J01031), the Program for Excellent Young Researchers in University of Fujian Province (No. JA10056), and the Project of Fujian Provincial Department of Education (No. JA11044).

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Abstract

The one-pot synthesis of novel calix[4]-bis-crowns and biscalix[4]crown with two kinds of bridging chains was described. Calix[4]arene was firstly reacted with N,N'-ethylenebis(2-chloroacetamide) in “1+1” condensation, and then triethylene glycol ditosylate was added directly to give a new biscalix[4]crown 4 with two kinds of bridging chains in “2+2” condensation. According to similar procedure, by successively reacting calix[4]arene with N,N'-ethylenebis(2-chloroacetamide), ethyl bromoacetate and diethylenetriamine, a new calix[4]-bis-crowns 5 with two kinds of bridging chains was prepared. Further reacting compound 5 with phenyl isothiocyanate afforded calix[4]-bis-crowns 6 with thiourea branched chain. The structures and conformation of new compounds were characterized by elemental analyses, ESI-MS, 1H NMR, etc.

Key words： calix[4]crown; biscalix[4]arene; synthesis; one-pot

Cite this article

YE Jin-Qi , YANG Fa-Fu , ZHANG Xiao-Yi , JIAO Zi-Yu , GUO Hong-Yu . One-Pot Syntheses of Calix[4]-bis-crowns and Biscalix[4]crown with Two Kinds of Bridging Chains[J]. Chinese Journal of Organic Chemistry, 2012 , 32(01) : 189 -192 . DOI: 10.6023/cjoc1105292

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