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Chinese Journal of Organic Chemistry >

2012 , Vol. 32 >Issue 02: 393 - 396

DOI: https://doi.org/10.6023/cjoc1012142

Notes

Synthesis of α-Amino Phosphonates from One-Pot Three- Component Condensation Catalyzed by Bamboo Char Sulfonic Acid

  • ZHOU Xiao-Hong ,
  • XU Qiong ,
  • LIANG Jing ,
  • FU Zai-Hui ,
  • YIN Du-Lin
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  • Key Laboratory of Resource Fine-Processing and Advanced Materials, Universities of Hunan Province, Hunan Engineering Laboratory for Petrochemical New Materials, Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081

Received date: 2011-02-14

  Revised date: 2011-07-14

  Online published: 2012-03-09

Supported by

Project supported by the National Natural Science Foundation of China (No. 20572021), and the Natural Science Foundation of Hunan Province (No. 09JJ5006).

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Abstract

By using fresh bamboo condensation raw material, bamboo char sulfonic acid was obtained via sulfuric acid charring and sulfonation, which catalyzed the one-pot three-component synthesis of α-amino phosphonates by condensation of various aromatic aldehydes with aromatic amines and diethyl phosphite. Experimental results have shown that bamboo char sulfonic acids have advantages of high activity, simplicity of operation, wide range of sources and easy recycle.

Key words： bamboo char sulfonic acid; heterogeneous catalysis; one-pot reaction; α-amino phosphonates

Cite this article

ZHOU Xiao-Hong , XU Qiong , LIANG Jing , FU Zai-Hui , YIN Du-Lin . Synthesis of α-Amino Phosphonates from One-Pot Three- Component Condensation Catalyzed by Bamboo Char Sulfonic Acid[J]. Chinese Journal of Organic Chemistry, 2012 , 32(02) : 393 -396 . DOI: 10.6023/cjoc1012142

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