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Photoinduced Single Electron Transfer Cyclization Reaction of N-(Amidosilane terminated polybenzylglycine peptide chain)-2,3-naphthalimide

  • Jin Yingxue ,
  • Wang Jiachang ,
  • Yue Qunfeng ,
  • Qu Fengyu ,
  • Wei Shuquan ,
  • Tan Guanghui
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  • College of Chemistry & Engineering, Harbin Normal University, Harbin 150025

Received date: 2011-11-09

  Revised date: 2011-12-09

  Online published: 2012-03-09

Supported by

Project supported by the National Natural Sciences Foundation of China (Nos. 20972036, 21171045), the Natural Sciences Foundation of Heilongjiang Province (No. B200913), and the Program for Scientific Technological Innovation Team Construction in Universites of Heilongjiang Province (No. 211TD010).

Abstract

Benzylglycine was used as starting material for the synthesis of novel intramolecular electron donor- accepter system N-(amidosilane terminated polybenzylglycine peptide chain)-2,3-naphthalimide(1). 1 could undergo a photoinduced single electron transfer cyclization reaction in MeOH-30% H2O solvent to provide novel cyclopolyglypeptides 2 in high regioselectivity. The structures of all the new compounds were characterized by MS and NMR techniques.

Cite this article

Jin Yingxue , Wang Jiachang , Yue Qunfeng , Qu Fengyu , Wei Shuquan , Tan Guanghui . Photoinduced Single Electron Transfer Cyclization Reaction of N-(Amidosilane terminated polybenzylglycine peptide chain)-2,3-naphthalimide[J]. Chinese Journal of Organic Chemistry, 2012 , 32(07) : 1290 -1295 . DOI: 10.6023/cjoc1111093

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