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Chinese Journal of Organic Chemistry >

2012 >Issue 03: 574 - 579

DOI: https://doi.org/10.6023/cjoc1109062

Articles

Study on the Coupling Reaction of Fuctionalized Bisorganozinc Iodides and Acyl Chlorides

  • Xu Changming ,
  • Yang Lei ,
  • Huang Danfeng ,
  • Niu Teng ,
  • Hu Yulai ,
  • Wang Kehu
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  • College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Received date: 2011-09-06

  Revised date: 2011-10-27

  Online published: 2012-03-24

Supported by

Project supported by the National Natural Science Foundation of China (No. 2072068), the Natural Science Foundation of Gansu Province (No. 3ZS041-A25-003), and the Specialized Research Fund of the Doctoral Propram of Higher Education (No. 200807360001).

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Abstract

This paper investigated the preparation of fuctionalized bisorganozinc iodides with ether, ester, carbonyl groups and the reactions with acyl chlorides in the presence of CuCN?2LiCl generating fuctionalized diketones. The method has the advantages of mild and simple reaction conditions with medium yields, and provides a simple synthesis procedure of fuctionalized long-chain diketone compounds.

Key words： bisorganozinc iodide; acyl chloride; diketone compound

Cite this article

Xu Changming , Yang Lei , Huang Danfeng , Niu Teng , Hu Yulai , Wang Kehu . Study on the Coupling Reaction of Fuctionalized Bisorganozinc Iodides and Acyl Chlorides[J]. Chinese Journal of Organic Chemistry, 2012 , (03) : 574 -579 . DOI: 10.6023/cjoc1109062

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