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Chinese Journal of Organic Chemistry >

2012 >Issue 03: 597 - 600

DOI: https://doi.org/10.6023/cjoc1106033

Notes

Chlorination Reaction of Disubstituted Alkenylboronic Acids

  • Xu Yan ,
  • Li Zhanxiong ,
  • Li Hui ,
  • Yang Jun
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  • a College of Textile and Clothing Engineering, Soochow University, Suzhou 215021;
    b Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received date: 2011-06-03

  Revised date: 2011-10-20

  Online published: 2012-03-24

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 91017006, 90917017, 90817008, 20802088).

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Abstract

The chlorination reaction of 4-substituted-1,2-oxaborol-2(5H)-ols with N-chlorosuccinimide (NCS) afford (Z)-2-substituted-3-chloroallyl alcohol in moderate to good yields under the optimized condition. The structures of the products were identified by 1H NMR, 13C NMR, FT-IR and MS techniques. This method is simple, mild, high yield and the configuration is maintained.

Key words： synthesis; alkenylboronic acid; chlorination; (Z)-2-substituted-3-chloro allyl alcohol

Cite this article

Xu Yan , Li Zhanxiong , Li Hui , Yang Jun . Chlorination Reaction of Disubstituted Alkenylboronic Acids[J]. Chinese Journal of Organic Chemistry, 2012 , (03) : 597 -600 . DOI: 10.6023/cjoc1106033

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