Articles

Synthesis and Photochromic Properties of Diarylethene-Based Porphyrin Derivative and Its Metal Complexes

  • Zheng Chunmei ,
  • Wang Tingting ,
  • Zeng Heping
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  • Institute of Functional Molecules, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641

Received date: 2011-04-17

  Revised date: 2011-11-07

  Online published: 2012-04-24

Supported by

Project supported by the National Natural Science Foundation of China (No. 21071054), the Science and Technology Planning Project of Guangdong Province (Nos. 2008B010800030, 2009B091300045), the Natural Science Foundation for the Doctoral Program of Guangdong Province (No. 9451064101003131) and the Fundamental Research Funds for the Central Universities (No 2009ZM0179).

Abstract

5-[2,3-Bis(2,4,5-trimethyl-3-thienyl)maleimide-N-phenyl]-10,15,20-triphenylorphyrin (TPPMA) and its Zn/Cu complexes have been synthesized using benzaldehyde and pyrrole as starting materials. Their structures were confirmed by 1H NMR and 13C NMR, IR, MS techniques. The photochromic properties were determined by UV-Vis spectra. The results indicated that TPPMA was non-photochromic under 254 nm light either in solid or liquid phase, while ZnTPPMA and CuTPPMA underwent reversible photochromic reactions under 254 and 650 nm light both in solution and in PVB amorphous film.

Cite this article

Zheng Chunmei , Wang Tingting , Zeng Heping . Synthesis and Photochromic Properties of Diarylethene-Based Porphyrin Derivative and Its Metal Complexes[J]. Chinese Journal of Organic Chemistry, 2012 , 32(04) : 719 -726 . DOI: 10.6023/cjoc1104172

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