Articles

Rapid and Highly Efficient Microwave-Assisted C—N, C—O and C— S Coupling Reactions without a Transition-Metal Catalyst

  • Yuan Yanqin ,
  • Guo Shengrong ,
  • Mo Jianjun ,
  • Qian Li ,
  • Shi Zefeng
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  • Department of Chemistry, Lishui University, Lishui 323000

Received date: 2011-08-30

  Revised date: 2011-11-03

  Online published: 2012-04-24

Supported by

Project supported by the Natural Science Foundation of Zhejiang Province (No. Y407240) and the Key Science Foundation of Lishui University (No. KZ20H03).

Abstract

A rapid and direct coupling reactions of various N/O/S nucleophilic reagents with aryl halides have been developed in good to high yields under microwave irradiation without a transition-metal catalyst. These reactions are a particularly powerful method for the coupling of electron-withdraw aryl halides with various nucleophilic reagents. A variety of products including aryl ethers, N-arylamides, and aryl thioethers were synthesized in good to excellent yields.

Cite this article

Yuan Yanqin , Guo Shengrong , Mo Jianjun , Qian Li , Shi Zefeng . Rapid and Highly Efficient Microwave-Assisted C—N, C—O and C— S Coupling Reactions without a Transition-Metal Catalyst[J]. Chinese Journal of Organic Chemistry, 2012 , 32(04) : 732 -741 . DOI: 10.6023/cjoc1108302

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