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Chinese Journal of Organic Chemistry >

2012 , Vol. 32 >Issue 04: 786 - 789

DOI: https://doi.org/10.6023/cjoc1107201

Notes

Synthesis of 2,3-Dimethyl-2,3-dinitrobutane by Oxidative Coupling of Acetone Oxime

  • Zhang Shengjian ,
  • Zhao Yingxian ,
  • Zhang Hong
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  • Ningbo Institute of Technology, Zhejiang University, Ningbo 315100

Received date: 2011-07-20

  Revised date: 2011-11-28

  Online published: 2012-04-24

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Abstract

2,3-Dimethyl-2,3-dinitrobutane (DMNB) was prepared by oxidative coupling of acetone oxime with H2O2 over the modified TS-1 catalyst. In one-pot operation, the ammoximation of acetone followed by catalytic oxidative coupling over TS-1 produced the DMNB with yield of 43.2%. The operation is simple and safe. The structures of products were identified by 1H NMR and 13C NMR spectra.

Key words： acetone oxime; oxidative coupling; hydrogen peroxide; 2,3-dimethyl-2,3-dinitrobutane; modified TS-1 catalyst

Cite this article

Zhang Shengjian , Zhao Yingxian , Zhang Hong . Synthesis of 2,3-Dimethyl-2,3-dinitrobutane by Oxidative Coupling of Acetone Oxime[J]. Chinese Journal of Organic Chemistry, 2012 , 32(04) : 786 -789 . DOI: 10.6023/cjoc1107201

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