Articles

Study on Lewis Acid Induced the Stille Cross-Coupling Reactions of Aryltriazenes as Substrates

  • Nan Guangming ,
  • Zhou Jun
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  • a Xinjiang Laboratory of Phase Transitions and Microstructures of Condensed Matters, College of Chemistry and Biology, Yili Normal University, Yining 835000;
    b Comprehensive Technical Service Centre of Yili Entry-exit Inspection and Quarantine Bureau, Yining 835000

Received date: 2012-01-31

  Revised date: 2012-05-18

  Online published: 2012-05-01

Supported by

Project supported by the National Natural Science Foundation of China (No.20962022), the Opening Project of Xinjiang Laboratory of Phase Transitions and Microstructures of Condensed Matters (No.2012YLSYnjt 01)

Abstract

The Stille cross-coupling reaction of aryltriazene as a novel electrophilic substrate has been realized for the first time. The reactions were performed at room temperature under an argon atmosphere. Solvents, molar ratio of aryltriazene/tributyl(phenyl)stannane, amount of catalyst were optimized and excellent yield was obtained. Aryltriazene via Lewis acid-assisted was transferred to palladium(II) compound. Cross-coupling reactions were catalyzed by palladium(II) compound. The products were purified via column chromatography on silica gel. Structures of all products were confirmed by 1H NMR and 13C NMR techniques.

Cite this article

Nan Guangming , Zhou Jun . Study on Lewis Acid Induced the Stille Cross-Coupling Reactions of Aryltriazenes as Substrates[J]. Chinese Journal of Organic Chemistry, 2012 , 32(9) : 1695 -1699 . DOI: 10.6023/cjoc1201311

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