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Synthesis, Characterization and Properties of Some Novel Structural Asymmetric Triarylamines

  • Li Yingjun ,
  • Zhao Nan ,
  • Li Lina ,
  • Li Chunyan ,
  • Sun Shuqin ,
  • Zhou Xiaoxia
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  • College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029

Received date: 2011-05-12

  Revised date: 2011-10-09

  Online published: 2012-01-06

Supported by

Project supported by the Natural Science Foundation of Liaoning Province (No. 20102126).

Abstract

Four structural asymmetric triarylamines were synthesized by diarylamines and 3,5-dimethyl-iodobenzene as the starting materials using Ullmann reaction. They are new compounds except the compound 1. The structures of the target compounds were characterized by IR, 1H NMR, 13C NMR, HRMS and elemental analysis. The optical, electrochemical, and thermal properties were examined. The results indicated that the synthesized compounds emitted green fluorescence in chloroform, and exhibited a good electrochemical and thermal stability. The synthesized triarylamines are potential hole-transporting materials and green-light-emitting materials.

Cite this article

Li Yingjun , Zhao Nan , Li Lina , Li Chunyan , Sun Shuqin , Zhou Xiaoxia . Synthesis, Characterization and Properties of Some Novel Structural Asymmetric Triarylamines[J]. Chinese Journal of Organic Chemistry, 2012 , 32(05) : 949 -952 . DOI: 10.6023/cjoc1105121

References

[1] Kurata, T.; Koshika, K.; Kato, F.; Kido, J.; Nishide, H. Polyhedron2007, 26, 1776.  

[2] Bellmann, E.; Shaheen, S. E.; Thayumanavan, S.; Barlow, S.;Grubbs, R. H.; Marder, S. R.; Kippelen, B.; Peyghambarian, N.Chem. Mater. 1998, 10, 1668.  

[3] Kim, Y. K.; Hwang, S. H. Synth. Met. 2006, 156, 1028.  

[4] Wang, Y.-G.; Ou, J.-B.; Xu, Q.-G.; Wu, L. Chin. J. Org. Chem.2006, 26(7), 992 (in Chinese).(王延广, 欧加保, 徐强国, 吴琳, 有机化学, 2006, 26(7), 992.)

[5] Shirota, Y. J. Mater. Chem. 2005, 15, 75.  

[6] Thelakkat, M. Macromol. Mater. Eng. 2002, 287, 442.  

[7] Bender, T. P.; Graham, J. F.; Duff, J. M. Chem. Mater. 2001, 13,4105.  

[8] Goodbrand, H. B.; Hu, N. X. J. Org. Chem. 1999, 64, 670.  

[9] J & K Chemical LTD Acros Organics Reference Handbook of FineChemicals, Beijing, 2006~2007, p. 1845.

[10] Promarak, V.; Ichikawa, M.; Meunmart, D.; Sudyoadsuk, T.;Saengsuwan, S.; Keawina, T. Tetrahedron Lett. 2006, 47, 8949.  

[11] Tan, C. X.; Feng, R. F.; Peng, X. X. Chin. Chem. Lett. 2007, 18,505.  

[12] Ding, B.-D.; Zhang, J.-M.; Zhu, W.-Q.; Zheng, X.-Y.; Wu, Y.-Z.;Jiang, X.-Y.; Zhang, Z.-L.; Xu, S.-H. Chin. J. Lumin. 2003, 24, 606(in Chinese).(丁邦东, 张积梅, 朱文清, 郑新友, 吴有智, 蒋雪茵, 张志林,许少鸿, 发光学报, 2003, 24, 606.)

[13] Tian, W.-J.; Wu, F.; Fan, Y.-G.; Shen, J.-C. Chin. J. Lumin. 2000,21, 230 (in Chinese).(田文晶, 吴芳, 樊玉国, 沈家骢, 发光学报, 2000, 21, 230.)
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