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Chinese Journal of Organic Chemistry >

2012 , Vol. 32 >Issue 05: 953 - 956

DOI: https://doi.org/10.6023/cjoc1107262

Notes

Synthesis and Properties of A Novel Naphthol-Substituted Tetrathiafulvalene Derivative

  • Zhao Bangtun ,
  • Liu Lianwei ,
  • Li Xiaochuan ,
  • Qu Guirong
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  • a Department of Chemistry, Luoyang Normal University, Luoyang 471022;
    b College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007

Received date: 2011-06-26

  Revised date: 2011-12-25

  Online published: 2012-01-06

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 20872058, 21172105).

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Abstract

A novel naphthol-substituted tetrathiafulvalene derivative 2 was conveniently synthesized and characterized by 1H NMR, 13C NMR, IR, MS techniques and elemental analysis. The recognition properties for 2 were carried out by CV (cyclic voltammetry) and fluorescence titration methods. The CV experiments show that compound 2 has apparent response to Zn2+ and Cd2+. Fluorescence titration experiments indicate that the fluorescence emission intensity of 2 has increased while the detected ions were added independently. Especially, while Zn2+ or Cd2+ was added, the fluorescence enhancement was more notable. Therefore, the compound 2 could serve as a dual optical-electrochemical chemosensor for Zn2+ and Cd2+ ions.

Key words： tetrathiafulvalene; naphthalene thiol; ions recognition

Cite this article

Zhao Bangtun , Liu Lianwei , Li Xiaochuan , Qu Guirong . Synthesis and Properties of A Novel Naphthol-Substituted Tetrathiafulvalene Derivative[J]. Chinese Journal of Organic Chemistry, 2012 , 32(05) : 953 -956 . DOI: 10.6023/cjoc1107262

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