Notes

Ruthenium-Catalyzed One-Pot Synthesis of Quinolines from Nitroarenes and Trialkylamines

  • Yang Huiqiong ,
  • Chen Ru ,
  • Deng Guojun
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  • a College of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104;
    b College of Chemistry, Xiangtan University, Xiangtan 411105

Received date: 2012-02-23

  Revised date: 2012-06-01

  Online published: 2012-05-16

Supported by

Project supported by the National Natural Science Foundation of China (No.20902076)

Abstract

A series of quinolines were synthesized in moderate yields by one-pot reaction of nitroarenes and trialkylamines in the presence of a catalytic amount of ruthenium trichloride catalyst together with tricyclohexylphosphonium tetrafluoroborate ligand. This method is convenient without extra reductant, and nitroarenes are cheap and highly available. The structures of the products were characterized by IR,1H NMR,13C NMR, MS techniques and elemental analysis.

Cite this article

Yang Huiqiong , Chen Ru , Deng Guojun . Ruthenium-Catalyzed One-Pot Synthesis of Quinolines from Nitroarenes and Trialkylamines[J]. Chinese Journal of Organic Chemistry, 2012 , 32(9) : 1725 -1731 . DOI: 10.6023/cjoc1202231

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