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Chinese Journal of Organic Chemistry >

2012 , Vol. 32 >Issue 08: 1439 - 1444

DOI: https://doi.org/10.6023/cjoc201205023

Articles

An Investigation on the Transition Metal Catalyzed Selective Additions of Styrenes with Diacetoxyiodobenzene (DIB)- Tetrabutylamidebromide (TBAB) System

  • Fan Lei ,
  • Ren Lingfeng ,
  • Chen Tian ,
  • Yi Rong ,
  • Yu Lei
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  • a School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093;
    b College of Chemistry & Materials Engineering, Wenzhou University, Wenzhou 325027;
    c School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002

Received date: 2012-05-17

  Revised date: 2012-06-05

  Online published: 2012-06-11

Supported by

Project supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions, the Opening Foundation of Zhejiang Provincial Top Key Discipline (No. 100061200138), the Natural Scientific Foundation of Jiangsu Province (No. BK2010321), the University Natural Scientific Foundation of Jiangsu Province (No. 09KJB150014) and the Opening Labortary Fundation of Jiangsu Province (No. K100027).

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Abstract

The transition metal catalyzed addition of diacetoxyiodobenzene (DIB)-tetrabutylamidebromide (TBAB) system with styrenes could introduce bromo and oxide groups to olefins. This reaction provides a high regio- and stereo-selective synthetic strategy and is much useful in organic synthesis.

Key words： catalysis; transition metal; regioselecticvity; stereoselecticvity; addition

Cite this article

Fan Lei , Ren Lingfeng , Chen Tian , Yi Rong , Yu Lei . An Investigation on the Transition Metal Catalyzed Selective Additions of Styrenes with Diacetoxyiodobenzene (DIB)- Tetrabutylamidebromide (TBAB) System[J]. Chinese Journal of Organic Chemistry, 2012 , 32(08) : 1439 -1444 . DOI: 10.6023/cjoc201205023

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