Chinese Journal of Organic Chemistry >
Transition Metal-Catalyzed Transformations of P(O)—H Bonds
Received date: 2012-07-18
Revised date: 2012-08-10
Online published: 2012-08-13
Organophosphorus compounds are of high importance in organic synthesis, catalysis, biochemistry, pharmaceuticals, and material science. In this account, we summarize our recent studies on transition metal-catalyzed transformations of P(O)—H compounds, mainly the regio- and stereo-selective additions of P(O)—H bonds to carbon—carbon unsaturated compounds, asymmetric hydrophosphorylation reactions, and oxidative/dehydrogenative cross-couplings of P(O)—H bonds with C—H and heteroatom—H bonds. These new reactions provided a series of efficient and atom economic, general and green ways for the preparation of a variety of versatile organophosphorus compounds. Mechanistic aspects related to the catalytic processes are also discussed.
Xu Qing , Zhao Changqiu , Zhou Yongbo , Yin Shuangfeng , Han Libiao . Transition Metal-Catalyzed Transformations of P(O)—H Bonds[J]. Chinese Journal of Organic Chemistry, 2012 , 32(10) : 1761 -1775 . DOI: 10.6023/cjoc201207024
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