Articles

Pd/C-Catalyzed Highly Efficient and Green Suzuki Cross-Coupling Reaction

  • Wang Man ,
  • Li Xinmin ,
  • Hou Yanjun ,
  • Sun Zhizhong
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  • a School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080;
    b Key Laboratory of Chemical Engineering Process & Technology for High-efficiency Conversion, College of Heilongjiang Province, Harbin 150080

Received date: 2012-06-30

  Revised date: 2012-07-18

  Online published: 2012-07-14

Supported by

Project supported by the Research Project of Education Department of Heilongjiang Province of China (No.12511383) and the Research Special Funds for Innovation Talent of Harbin of China (No.RC2012XK001005)

Abstract

An efficient protocol for the Suzuki reaction catalyzed by Pd/C has been developed in a green sovent. This method is able to prepare a variety of biaryls in high yields. In the presence of 1-butyl-3-methylimidazolium bis[(trifluoro-methyl)sulfonyl]imide, the cross-coupling reaction of aryl bromides with arylboronic acids proceed smoothly in PEG400 aqueous at 45℃. The catalyst could be recycled four times without loss of activity.

Cite this article

Wang Man , Li Xinmin , Hou Yanjun , Sun Zhizhong . Pd/C-Catalyzed Highly Efficient and Green Suzuki Cross-Coupling Reaction[J]. Chinese Journal of Organic Chemistry, 2012 , 32(9) : 1666 -1672 . DOI: 10.6023/cjoc201206029

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