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Chinese Journal of Organic Chemistry >

2013 , Vol. 33 >Issue 02: 359 - 364

DOI: https://doi.org/10.6023/cjoc201209016

Articles

Rapid Identification of Synthetic Compounds in Natural Repellent Products by Direct Analysis in Real Time Mass Spectrometry

  • Qi Wanshu ,
  • Zhang Li ,
  • Guo Yinlong
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  • Shanghai Mass Spectrometry Center, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032

Received date: 2012-09-11

  Revised date: 2012-10-12

  Online published: 2012-10-16

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21202192, 21275155) and the Innovation Method Fund of China (Nos. 2011IM030200, 2011IM030400, 2011IM030700).

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Abstract

A rapid and simple method for identification of the synthetic repellent compounds such as DEET and BAAPE has been developed based on direct analysis in real time mass spectrometry (DART-MS). Through this method, the synthetic compounds in natural repellent products can be identified by comparison of characteristic mass spectrometric signals. Without any sample pretreatment, all of these were achieved at room temperature and atmospheric pressure. This method greatly reduces the analysis time, with the advantages of accurate, high throughput and in situ.

Key words： direct analysis in real time (DART); mass spectrometry; insect repellent; rapid identification

Cite this article

Qi Wanshu , Zhang Li , Guo Yinlong . Rapid Identification of Synthetic Compounds in Natural Repellent Products by Direct Analysis in Real Time Mass Spectrometry[J]. Chinese Journal of Organic Chemistry, 2013 , 33(02) : 359 -364 . DOI: 10.6023/cjoc201209016

References

[1] Fradin, M. S. Annals Int ern. Med. 1998, 128, 931.

[2] Marta Ferreira Maia; Moore, S. J. Malar. J. 2011, 10, S11.

[3][3] Costantini, C.; Badolo, A.; Ilboudo-Sanogo, E. Trans. R. Soc. Trop. Med. Hyg. 2004, 98, 644.

[4] Syed, Z.; Leal, W. S. Proc. Natl. Acad. Sci. U. S. A. 2008, 105, 13598.

[5] Licciardi, S.; Herve, J. P.; Darriet, F.; Hougard, J. M.; Corbel, V. Med. Vet. Entomol. 2006, 20, 288.

[6] Koren, G.; Matsui, D.; Bailey, B. Can. Med. Assoc. J. 2003, 169, 209.

[7] Corbel, V.; Stankiewicz, M.; Pennetier, C.; Fournier, D.; Stojan, J.; Girard, E.; Dimitrov, M.; Molgo, J.; Hougard, J.-M.; Lapied, B. BMC Biol. 2009, 7, 47.

[8] Pietrogrande, M. C.; Basaglia, G. TrAC, Trends Anal. Chem. 2007, 26, 1086.

[9] Trenholm, R. A.; Vanderford, B. J.; Holady, J. C.; Rexing, D. J.; Snyder, S. A. Chemosphere 2006, 65, 1990.

[10] Peck, A. Anal. Bioanal. Chem. 2006, 386, 907.

[11] Marselos, S. C.; Archontaki, H. A. J. Chromatogr., A 2002, 946, 295.

[12].Venter, A.; Nefliu, M.; Cooks, R. G. TrAC, Trends Anal. Chem. 2008, 27, 284.

[13] Cody, R. B.; Laramee, J. A.; Durst, H. D. Anal. Chem. 2005, 77, 2297.

[14] Petucci, C.; Diffendal, J.; Kaufman, D.; Mekonnen, B.; Terefenko, G.; Musselman, B. Anal. Chem. 2007, 79, 5064.

[15] Yu, S.; Crawford, E.; Tice, J.; Musselman, B.; Wu, J.-T. Anal. Chem. 2009, 81, 193.

[16] Zhou, Z.; Zhang, J.; Zhang, W.; Bai, Y.; Liu, H. Analyst 2011, 136, 2613.

[17] Grange, A. H.; Sovocool, G. W. Rapid Commun. Mass Spectrom. 2011, 25, 1271.

[18] Cheng, X. L.; Li, W. J.; Li, W. J.; Wei, F.; Xiao, X. Y.; Lin, R. C. Chin. J. Pharm. Anal. 2011, 31, 438 (in Chinese). (程显隆, 李文杰, 李卫健, 魏锋, 肖新月, 林瑞超, 药物分析杂志, 2011, 31, 438.)

[19] Bennett, M. J.; Steiner, R. R. J. Forensic Sci. 2009, 54, 370.

[20] Steiner, R. R.; Larson, R. L. J. Forensic Sci. 2009, 54, 617.

[21] Howlett, S. E.; Steiner, R. R. J. Forensic Sci. 2011, 56, 1261.

[22] Samms, W. C.; Jiang, Y. J.; Dixon, M. D.; Houck, S. S.; Mozayani, A. J. Forensic Sci. 2011, 56, 993.

[23] Nath, M.; Saini, P. K.; Eng, G.; Song, X. J. Organomet. Chem. 2008, 693, 2271.

[24] Watts, K. R.; Loveridge, S. T.; Tenney, K.; Media, J.; Valeriote, F. A.; Crews, P. J. Org. Chem. 2011, 76, 6201.

[25] Sanchez, L. M.; Curtis, M. E.; Bracamonte, B. E.; Kurita, K. L.; Navarro, G.; Sparkman, O. D.; Linington, R. G. Org. Lett. 2011, 13, 3770.

[26] Vaclavik, L.; Cajka, T.; Hrbek, V.; Hajslova, J. Anal. Chim. Acta 2009, 645, 56.

[27] Vaclavik, L.; Rosmus, J.; Popping, B.; Hajslova, J. J. Chromatogr., A 2010, 1217, 4204.

[28] Crawford, E.; Musselman, B. Anal. Bioanal. Chem. 2012, 403, 2807.

[29] Schurek, J.; Vaclavik, L.; Hooijerink, H.; Lacina, O.; Poustka, J.; Sharman, M.; Caldow, M.; Nielen, M. W. F.; Hajslova, J. Anal. Chem. 2008, 80, 9567.

[30] Zhang, J.; Zhou, Z.; Yang, J.; Zhang, W.; Bai, Y.; Liu, H. Anal. Chem. 2012, 84, 1496.

[31] Yu, Q.; Yu, B. B.; Yue, H.; Jiao, L. L.; Liu, S. Y. Acta Chim. Sinica 2012, 70, 1650 (in Chinese). (于擎, 于彬彬, 越皓, 焦丽丽, 刘淑莹, 化学学报, 2012, 70, 1650.)

[32] Zhang, J. L.; Huo, F. F.; Zhou, Z. G.; Bai, Y.; Liu, H. W. Prog. Chem. 2012, 24, 101 (in Chinese). (张佳玲, 霍飞凤, 周志贵, 白玉, 刘虎威, 化学进展, 2012, 24, 101.)
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