Chinese Journal of Organic Chemistry >
Base-Free Cu(II)-Catalyzed Coupling Reaction of Arylboronic Acids and Thiols
Received date: 2012-09-06
Revised date: 2012-10-17
Online published: 2012-10-25
Supported by
Project supported by the Natural Science Foundation of Zhejiang Province (No. Y407081).
Baes-free Cu(II)-catalyzed coupling reaction of arylboronic acid and thiols was described. After optimization of reaction conditions, such as solvents, reaction temperatures, copper salts and ligands, the results show that some biarylsulfides were synthesized in good yields using 1,10-phenanthroline-Cu(OAc)2·H2O as catalyst, DMSO/H2O (V: V＝1:1) as solvent, under air atmosphere at 60℃.
Key words： coupling reaction; thiol; arylboronic acid; 1,10-phenanthroline; cupric acetate
Yang Minghua , Pei Ji , Yan Guobing , Weng Qiuyue . Base-Free Cu(II)-Catalyzed Coupling Reaction of Arylboronic Acids and Thiols[J]. Chinese Journal of Organic Chemistry, 2013 , 33(02) : 343 -347 . DOI: 10.6023/cjoc201209008
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