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Chinese Journal of Organic Chemistry >

2013 , Vol. 33 >Issue 02: 319 - 324

DOI: https://doi.org/10.6023/cjoc201210004

Articles

Ligand-Free Pd-Catalyzed Cross-Coupling Reaction of Olefins and Trialkoxyarylsilanes

  • Tang Boxiao ,
  • Fang Xiaoniu ,
  • Kuang Renyun ,
  • Zhou Xiaochun
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  • School of Chemistry and Chemical Engineering, Institute of Applied Chemistry, and Key Laboratory of Coordination Chemistry of Jiangxi Province, Jinggangshan University, Ji'an 343009

Received date: 2012-10-07

  Revised date: 2012-11-15

  Online published: 2012-11-20

Supported by

Project supported by the Science and Technology Project of Jiangxi Provincial Department of Education (No. GJJ12471) and the Doctoral Program of Jinggangshan University (No. JZ10042).

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Abstract

A ligand-free Pd-catalyzed method was developed for Heck-type reaction of a wide range of olefins with various trialkoxyarylsilanes. In the presence of Pd(OAc)2, K2CO3, TBAF?3H2O and AgOAc, the cross-coupling products can be obtained in moderate to good yields, and the Heck-type reaction displayed high regio- and stereo-selectivities. The mechanism of Heck-type reaction was discussed according to our experimental results and the reported mechanism.

Key words： ligand-free; palladium-catalyst; Heck-type reaction; trialkoxyarylsilanes

Cite this article

Tang Boxiao , Fang Xiaoniu , Kuang Renyun , Zhou Xiaochun . Ligand-Free Pd-Catalyzed Cross-Coupling Reaction of Olefins and Trialkoxyarylsilanes[J]. Chinese Journal of Organic Chemistry, 2013 , 33(02) : 319 -324 . DOI: 10.6023/cjoc201210004

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