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Chinese Journal of Organic Chemistry >

2013 , Vol. 33 >Issue 03: 542 - 550

DOI: https://doi.org/10.6023/cjoc201211018

Articles

Synthesis, Crystal Structure and Herbicidal Activity of Novel Sulfonylureas Containing Triazolinone Moiety

  • Pan Li ,
  • Chen Youwei ,
  • Liu Zhuo ,
  • Li Yonghong ,
  • Li Zhengming
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  • Research Institute of Elemento-organic Chemistry, State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071

Received date: 2012-11-08

  Revised date: 2012-12-12

  Online published: 2012-12-18

Supported by

Project supported by the National Natural Science Foundation of China (No. 21272129), the National Basic Research Program of China (No. 2010CB126106) and the National Key Technologies R&D Program (No. 2011BAE06B05).

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Abstract

In order to search for efficient sulfonylurea herbicides, the title compounds were designed by introducing triazolinones into some known sulfonylurea structures. 23 novel sulfonylurea compounds had been synthesized and characterized by 1H NMR, HRMS and X-ray diffraction. Herbicidal activities of title compounds were determined by pot-culture method. IC50 values of some effective sulfonylurea compounds were tested by culture dish method. It was found that compound 5h attained the super-active level which was comparable to the controls as triasulfuron and cinosulfuron. It was worthy to note that compound 5h had potent inhibitory activity against Echinochloa crusgalli by pot-culture method at 3.75 g/ha.

Key words： sulfonylurea; triazolinone; synthesis; crystal structure; herbicidal activity

Cite this article

Pan Li , Chen Youwei , Liu Zhuo , Li Yonghong , Li Zhengming . Synthesis, Crystal Structure and Herbicidal Activity of Novel Sulfonylureas Containing Triazolinone Moiety[J]. Chinese Journal of Organic Chemistry, 2013 , 33(03) : 542 -550 . DOI: 10.6023/cjoc201211018

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