Reviews

Development on the Synthesis of Ring Expanded N-Heterocyclic Carbene Precursors

  • Yang Liangru ,
  • Wei Dong ,
  • Mai Wenpeng ,
  • Mao Pu
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  • School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001

Received date: 2012-11-19

  Revised date: 2012-12-10

  Online published: 2012-12-18

Supported by

Project supported by the National Natural Science Foundation of China (No. 21172055), the Plan for Scientific Innovation Talent (No. 11CXRC10) & Doctoral Scientific Fund Project (No. 2009BS010) of Henan University of Technology.

Abstract

As a kind of novel developed ligands, N-heterocyclic carbenes (NHCs) play very important roles in the development of modern organic chemistry. Early studies on NHCs have been mainly focused on imidazole derived five membered heterocycles, due to their easy accessibility and comparably stable properties. Recently, ring expanded NHCs, such as six- or seven-membered NHCs became another research hot spot due to their steric characteristics and chemical properties. Because deprotonation of the heterocyclic onium salt precursors is by far the most commonly used method to access NHCs, the synthesis of the precursors remains a key factor affecting the development of ring expanded NHCs. This review will summarize the progress on the synthesis of ring expanded NHC precursors.

Cite this article

Yang Liangru , Wei Dong , Mai Wenpeng , Mao Pu . Development on the Synthesis of Ring Expanded N-Heterocyclic Carbene Precursors[J]. Chinese Journal of Organic Chemistry, 2013 , 33(05) : 943 -953 . DOI: 10.6023/cjoc201211035

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