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Chinese Journal of Organic Chemistry >

2013 , Vol. 33 >Issue 05: 1042 - 1046

DOI: https://doi.org/10.6023/cjoc201212013

Articles

Synthesis and Properties of the Polymer Based on Benzoxazine with Two Perfluorohexyl Side Chains

  • Wu Jianping ,
  • Lai Hua ,
  • Diao Shen ,
  • Jin Kaikai ,
  • Yuan Chao ,
  • Fang Qiang
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  • a East China University of Science & Technology, School of Materials Science and Engineering, Shanghai 200237;
    b Key Laboratory of Organofluorine Chemistry and Laboratory for Polymer Materials, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received date: 2012-12-11

  Revised date: 2013-01-06

  Online published: 2012-01-09

Supported by

Project supported by the Ministry of Science and Technology of China (No. 2011ZX02703).

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Abstract

A new benzoxazine with two perfluorohexyl side chains (M1) was synthesized and its homopolymerization was investigated. The results showed that the curing of M1 was occurred at near 257 ℃, whereas the curing onset temperature can be lowered to 183 ℃ when a catalyst of 5 wt% imidazole was added. The cured M1 exhibited higher thermal stability with 5% and 10% weight loss temperatures of 337 and 382 ℃, and a char yield of 45.9%, respectively. The cured M1 exhibited also good electrical properties with dielectric constant of 3.78 in a frequency of 1 MHz. The water absorption of the cured M1 was below 1%, and the surface free energy was 6.98 mN/m, respectively.

Key words： benzoxaizne; thermal stability; dielectric constant; water absorbance; surface property

Cite this article

Wu Jianping , Lai Hua , Diao Shen , Jin Kaikai , Yuan Chao , Fang Qiang . Synthesis and Properties of the Polymer Based on Benzoxazine with Two Perfluorohexyl Side Chains[J]. Chinese Journal of Organic Chemistry, 2013 , 33(05) : 1042 -1046 . DOI: 10.6023/cjoc201212013

References

[1] Ishida, H.; Low, H. Y. Macromolecules 1997, 30, 1099.
[2] Ning, X.; Ishida, H. J. Polym. Sci.: Part B: Polym. Phys. 1994, 32, 921.
[3] Ishida, H.; Allen, D. J. Polym. Sci.: Part B: Polym. Phys. 1996, 34, 1019.
[4] Takeichi, T.; Zeidam, R.; Agag, T. Polymer 2002, 43, 45.
[5] Lee, Y. J.; Huang, J. M.; Kuo, S. W. Polymer 2005, 46, 2320.
[6] Ishida, H.; Low, H. Y. J. Appl. Polym. Sci. 1998, 69, 2559.
[7] Mantana, K.; Nantaya, Y. Polym. Polym. Compos. 2001, 9, 367.
[8] Su, Y. C.; Chang, F. C. Polymer 2003, 44, 7989.
[9] Lin, C. H. J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 4970.
[10] Lui, J. P.; Ishida, H. Polym. Polym. Compos. 2002, 10, 191.
[11] Pedro, V. H.; Ishida, H. J. Fluorine Chem. 2009, 13, 573.
[12] Pedro, V. H. Macromolecules 2008, 41, 9704.
[13] Shi, Z. X.; Pan, Y.; Wang, Y. Z; Yu, D. S. J. Beijing Univ. Chem. Technol. 2000, 27, 13 (in Chinese).
(史子兴, 潘颖, 王一中, 余鼎声, 北京化工大学学报, 2000, 27, 13.)
[14] Chen, X. P. RCS Adv. 2012, 2, 6504.
[15] Lin, C.H.; Chang, S. L. Polymer 2008, 49, 1220.
[16] Kureshy, R. I. Tetrahedron: Asymmetry 2001, 12, 433.
[17] Mohan, N. W.; Wolter, F. J. J. Org. Chem. 2010, 75, 6814.
[18] Brunovska, Z.; Liu, J. Macromol. Chem. Phys. 1999, 200, 1745.
[19] Kim, H. D.; Ishida H. Macromolecules 2003, 36, 8320.
[20] Liu. C.; Shen D. M. Macromolecules 2011, 44, 4616.
[21] Maier, G. Prog. Polym. Sci. 2001, 26, 3.
[22] Hougham, G.; Tesoro, G.; Viehbeck, A.; Chapple-Sokol, J. D. Macromolecules 1994, 27, 5964.
[23] Sun, T.; Wang, G.; Feng, L. Angew. Chem. 2004, 116, 361.
[24] Sehonhorn, H. Macromolecules 1968, 1, 145.
[25] Katano, Y.; Tomono, H. Macromolecules 1994, 27, 2342.
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