Articles

Selenium-Promoted Homocoupling of Grignard Reagents

  • Tang Jinpeng ,
  • Tang Yu ,
  • Yang Jun ,
  • Zhang Yuanming
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  • Department of Chemistry, College of Life Science and Technology, Jinan University, Guangzhou 510632

Received date: 2012-12-20

  Revised date: 2013-01-19

  Online published: 2013-01-23

Supported by

Project supported by the National University Student Innovative Program (No. 101055920).

Abstract

The optimized reacting conditions were obtained by exploring the amount of magnesium and selenium, and the influence of catalysts and ligands. 15 homo-coupling aromatic or aliphatic products were obtained in high isolated yields of 65%~92%. A reasonable mechanism of selenium cycling in reaction was proposed based on experimental results.

Cite this article

Tang Jinpeng , Tang Yu , Yang Jun , Zhang Yuanming . Selenium-Promoted Homocoupling of Grignard Reagents[J]. Chinese Journal of Organic Chemistry, 2013 , 33(05) : 1010 -1014 . DOI: 10.6023/cjoc201212030

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