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Chinese Journal of Organic Chemistry >

2013 , Vol. 33 >Issue 04: 749 - 759

DOI: https://doi.org/10.6023/cjoc201301032

Reviews

Chiral Polymetallic Catalysts and Their Applications in Asymmetric Catalysis

  • Li Kun ,
  • Yang Guoqiang ,
  • Liu Yuanyuan ,
  • Zhang Wanbin
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  • School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240

Received date: 2013-01-14

  Revised date: 2013-02-14

  Online published: 2013-02-22

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 20972095, 21172143 and 21232004) and the Science and Technology Commission of Shanghai Municipality (No. 09JC1407800).

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Abstract

Polymetallic catalytic process is the main metabolic way of life, which is widely observed in nature. Compared to the mono-metal catalysts, the designs and applications of polymetallic catalysts with high reactivity and enantioselectivity have been a hot research topic in organic chemistry recently. This review covers the recent research process on representative types of bimetallic catalysts, including hetero-bimetallic catalysts and dinuclear homometal catalysts, their reaction mechanisms and developments. Moreover, potentially development of this area is also discussed.

Key words： asymmetric catalysis; polymetallic; dinuclear homometal catalyst; hetero-bimetallic catalyst

Cite this article

Li Kun , Yang Guoqiang , Liu Yuanyuan , Zhang Wanbin . Chiral Polymetallic Catalysts and Their Applications in Asymmetric Catalysis[J]. Chinese Journal of Organic Chemistry, 2013 , 33(04) : 749 -759 . DOI: 10.6023/cjoc201301032

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