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Chinese Journal of Organic Chemistry >

2013 , Vol. 33 >Issue 04: 663 - 674

DOI: https://doi.org/10.6023/cjoc201301085

ACCOUNT

Development of Pincer Catalysts with Selected Group 8～10 Metals

  • Hao Xinqi ,
  • Niu Junlong ,
  • Zhao Xuemei ,
  • Gong Junfang ,
  • Song Maoping
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  • College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001

Received date: 2013-01-31

  Revised date: 2013-03-05

  Online published: 2013-03-06

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 20572102, 20872133, 20972141).

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Abstract

Pincer metal complexes have been widely applied in organic synthesis, organometallic catalysis and materials science. In this account, we trace our studies on the synthesis of pincer complexes of selected group 8～10 metals and their applications in catalytic reactions. Successful examples include achiral and chiral PCP pincer Pd(II) complexes, PCN pincer complexes of Pd(II) and Ni(II), bis(imidazolinyl)phenyl NCN pincer complexes of Pd(II), Pt(II), Ni(II), Rh(III) and Ir(III), NCN' pincer Pd(II) complexes and CNN' pincer complexes of Pd(II) and Ru(II), which are conveniently prepared from easily available starting materials via direct Caryl—H bond activation. Particularly, a one-pot phosphorylation/metalation strategy was developed, providing a new and facile approach for the preparation of PCP and PCN pincer metal complexes. The method avoids the troublesome isolation of the unstable P-containing ligands and meanwhile accomplishes the metalation of the related ligands central C—H bond in good yields, and the synthetic procedures are thus simplified. The obtained pincer metal complexes have been used as catalysts in various C—C bond-forming reactions including the asymmetric ones, transfer hydrogenation of ketones and asymmetric hydrophosphination. The related literature results are also presented.

Key words： pincer metal complex; C—H bond activation; one-pot phosphorylation/metalation; bis(imidazolinyl)phenyl; chiral; unsymmetrical; group 8～10 metals; catalysis

Cite this article

Hao Xinqi , Niu Junlong , Zhao Xuemei , Gong Junfang , Song Maoping . Development of Pincer Catalysts with Selected Group 8～10 Metals[J]. Chinese Journal of Organic Chemistry, 2013 , 33(04) : 663 -674 . DOI: 10.6023/cjoc201301085

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