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Chinese Journal of Organic Chemistry >

2013 , Vol. 33 >Issue 04: 835 - 839

DOI: https://doi.org/10.6023/cjoc201301057

Articles

Friedel-Crafts Reaction of Ferrocenyl Alcohol Catalyzed by [BPy][HSO4] in Water Phase

  • Sheng Wanli ,
  • Tian Fuli ,
  • Du Yuying ,
  • Wu Chunyu
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  • a Department of Chemistry, College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021;
    b Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051

Received date: 2013-01-23

  Revised date: 2013-03-06

  Online published: 2013-03-14

Supported by

Project supported by the National Natural Science Foundation of China (No. 21265010).

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Abstract

A novel, environment friendly and efficient methodology for the synthesis of a series of ferrocenyl compounds using the functionalized acid ionic liquid [BPy][HSO4] as catalyst in water under mild conditions is reported. The Friedel-Crafts reaction of ferrocenyl alcohol with nucleophiles could be carried out efficiently in an “aqueous dispersion” and the corresponding ferrocenyl compounds were obtained in good to excellent yields. Suitable crystal of 3i was obtained, and the X-ray diffraction analysis indicated that compound 3i belonged to triclinic, space group P-1. The procedure reported here has the advantages of mild reaction conditions, high yields, operational simplicity and catalyst recyclability.

Key words： [BPy][HSO4] ionic liquid; Friedel-Crafts recation; catalysis; crystal structure

Cite this article

Sheng Wanli , Tian Fuli , Du Yuying , Wu Chunyu . Friedel-Crafts Reaction of Ferrocenyl Alcohol Catalyzed by [BPy][HSO4] in Water Phase[J]. Chinese Journal of Organic Chemistry, 2013 , 33(04) : 835 -839 . DOI: 10.6023/cjoc201301057

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