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Chinese Journal of Organic Chemistry >

2013 , Vol. 33 >Issue 04: 704 - 714

DOI: https://doi.org/10.6023/cjoc201301065

Reviews

Progress in the Transition-Metal Catalyzed Oxidation of Tertiary Amines

  • Li Yuanming ,
  • Ma Lina ,
  • Li Zhiping
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  • Department of Chemistry, Renmin University of China, Beijing 100872

Received date: 2013-01-25

  Revised date: 2013-03-19

  Online published: 2013-03-22

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21072223, 21272267), the Fundamental Research Funds for the Central Universities, and the Research Funds of Renmin University of China (No. 10XNL017).

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Abstract

The oxidation of tertiary amines is an improtant process in nature. In chemistry, organic chemists have made great efforts to study on the simulation of enzymatic funtion of oxidation with transition metal catalyst. It provide us new and efficient protocols for the synthesis of nitrogen compounds. The catalytic reactions also enhances our understanding the mechanism of the oxidation of tertiary amins in living system. During this decade, significant progress has been made in the transition metal catalyzed oxidation of tertiary amines. This review is summarized by five types of oxidative transformation of tertiary amines: (1) synthesis of N-oxides of tertiary amines; (2) oxidative Mannich reaction of tertiary amines; (3) oxidative demethylation of tertiary amines; (4) oxidative amidation of tertiary amines; (5) oxidative transformation of the substituents of tertiary amines.

Key words： tertiary amine; oxidation; transition-metal catalysis; demethylation; amide

Cite this article

Li Yuanming , Ma Lina , Li Zhiping . Progress in the Transition-Metal Catalyzed Oxidation of Tertiary Amines[J]. Chinese Journal of Organic Chemistry, 2013 , 33(04) : 704 -714 . DOI: 10.6023/cjoc201301065

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