Chinese Journal of Organic Chemistry >
Research Progress in Friedel-Crafts Reaction of Indoles and Nitroalkenes
Received date: 2013-01-21
Revised date: 2013-03-18
Online published: 2013-04-07
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21262034, 20962018, 20862015, 20562011)
Indoles, as the core structure, exist widely in many alkaloid natural products and pharmaceuticals. The derivatives of indole play an important role in organism physiological activities. The Friedel-Crafts reaction of indoles and nitroalkenes is an important method to generate indole derivatives. According to the kinds of the catalyst in the reaction, the Friedel-Crafts reactions of indoles and nitroalkenes were summarized in this paper as follows: (1) catalyst-free, (2) ionic liquid catalyst, (3) metal salt catalyst, (4) coordination compound catalyst, (5) Brønsted acid catalyst, (6) small molecular organic catalyst, (7) other catalysts.
Key words： Friedel-Crafts reaction; indole; nitroolefin; catalyst
Wang Chunchao , Xie Shaolei , Xie Zhengfeng . Research Progress in Friedel-Crafts Reaction of Indoles and Nitroalkenes[J]. Chinese Journal of Organic Chemistry, 2013 , 33(9) : 1919 -1931 . DOI: 10.6023/cjoc201301051
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