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Chinese Journal of Organic Chemistry >

2013 , Vol. 33 >Issue 08: 1834 - 1838

DOI: https://doi.org/10.6023/cjoc201301055

Notes

Bis-thiocarbohydrazones Schiff Base Mn(II) Complex as a Catalyst for Henry Reaction

  • Zhang Peng ,
  • He Jun ,
  • Wan Ningning ,
  • Zhang Weidong ,
  • Hui Yonghai ,
  • Xie Zhengfeng
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  • a Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Urumqi 830046;
    b Oil Refinery of Petrochina Dushanzi Petrochemical Company, Dushanzi 833600

Received date: 2013-01-22

  Revised date: 2013-03-23

  Online published: 2013-04-07

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21262034, 20962018, 20862015, 20562011).

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Abstract

Bis-thiocarbohydrazones Schiff base Mn(II) complex catalyzes the Henry reaction between aldehydes and nitromethane to afford β-nitroalcohol derivatives at room temperature. The remarkable advantages of this reaction were mild reaction conditions, simple workup procedure, high yield of products, less catalyst and environmental friendly.

Key words： Henry reaction; aldehydes; nitromethane; Schiff base

Cite this article

Zhang Peng , He Jun , Wan Ningning , Zhang Weidong , Hui Yonghai , Xie Zhengfeng . Bis-thiocarbohydrazones Schiff Base Mn(II) Complex as a Catalyst for Henry Reaction[J]. Chinese Journal of Organic Chemistry, 2013 , 33(08) : 1834 -1838 . DOI: 10.6023/cjoc201301055

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