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Chinese Journal of Organic Chemistry >

2013 , Vol. 33 >Issue 08: 1595 - 1615

DOI: https://doi.org/10.6023/cjoc201303038

Reviews

Metal Catalysis versus Organocatalysis in the Catalytic Asymmetric Synthesis of 3-Hydroxyoxindole

  • Liu Yunlin ,
  • Zhu Feng ,
  • Wang Cuihong ,
  • Zhou Jian
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  • Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062

Received date: 2013-03-24

  Revised date: 2013-04-13

  Online published: 2013-04-24

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 20902025, 21172075), the National Basic Research Program of China (973 Program, No. 2011CB808600), the Program for New Century Excellent Talents in University (No. NCET-11-0147), the Scholarship Award for Excellent Doctoral Student Granted by Ministry of Education (No. MXRZZ2012007).

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Abstract

3-Substituted 3-hydroxyoxindoles are widely encountered in a large number of natural products, drugs and pharmaceutically active compounds. The catalytic asymmetric construction of this privileged skeleton has attracted great attention from synthetic chemistry, and much progress has been made in recent years. This review summarizes the advances in the catalytic enantioselective synthesis of four important types of subunits of 3-substituted 3-hydroxyoxindoles, and focuses on the discussion of the differences and advantages of metal catalysis and organocatalysis.

Key words： 3-substituted-3-hydroxyoxindole; asymmetric catalysis; metal catalysis; organocatalysis

Cite this article

Liu Yunlin , Zhu Feng , Wang Cuihong , Zhou Jian . Metal Catalysis versus Organocatalysis in the Catalytic Asymmetric Synthesis of 3-Hydroxyoxindole[J]. Chinese Journal of Organic Chemistry, 2013 , 33(08) : 1595 -1615 . DOI: 10.6023/cjoc201303038

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