Notes

Tetrabutylammonium Iodide-Catalyzed Phosphonation of sp3-C—H Bonds

  • Wang Qian ,
  • Xu Zhou
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  • Experimental Center for Biochemistry and Chemistry Teaching, School of Basic Sciences, Xuzhou Medical College, Xuzhou 221004

Received date: 2013-05-30

  Revised date: 2013-07-08

  Online published: 2013-07-11

Supported by

Project supported by the Natural Science Foundation of Higher Education Institutions of Jiangsu Province (No. 10KJB150018).

Abstract

Activation of sp3-C—H bonds and oxidative phosphonation of sp3-C—H bonds adjacent to a nitrogen atom of tertiary amine were catalyzed by tetrabutylammonium iodide (TBAI) with t-butylhydroperoxide (TBHP) as oxidant under mild reaction conditions. The safe, convenient, and environmentally benign process, as well as the broad substrate scope, low catalyst loading, high selectivity, short reaction time, and good yields make the protocol very practical.

Cite this article

Wang Qian , Xu Zhou . Tetrabutylammonium Iodide-Catalyzed Phosphonation of sp3-C—H Bonds[J]. Chinese Journal of Organic Chemistry, 2013 , 33(11) : 2430 -2434 . DOI: 10.6023/cjoc201305052

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