Chinese Journal of Organic Chemistry >
Progresses on Synthesis and Applications of Bis(cyclopentadieny)titanacycles
Received date: 2013-10-10
Revised date: 2013-12-30
Online published: 2014-01-10
Supported by
Project supported by the National Natural Science Foundation of China (No. 20972037), the Special Funds for Key Innovation Team of Zhejiang Province (No. 2010R50017), the Excellent Young Teacher Support Program of Hangzhou Normal University (No. 2011-01-013) and the Program for Changjiang Scholars and Innovative Research Team in Chinese University (No. IRT 1231).
Titanacycles, containing two carbon metal bonds in the molecule, have emerged as a series of significant intermediates in organic synthesis. The structural characteristics, preparation and synthetic applications of bis(cyclopentadienyl)titana-three, four, five, or six-membered rings have been summarized in the present review, in which the selective cleavage and reactivity of C—Ti bond in the titanacyle have been discussed.
Wang Ping , Zhang Yanjing , Wang Wei , Zheng Weixin . Progresses on Synthesis and Applications of Bis(cyclopentadieny)titanacycles[J]. Chinese Journal of Organic Chemistry, 2014 , 34(5) : 865 -875 . DOI: 10.6023/cjoc201310007
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