Chinese Journal of Organic Chemistry >
Synthetic and Structural Studies on Indenyl Phosphine Gold Complexes and Application as Catalyst for Hydration of Alkynes
Received date: 2014-01-23
Revised date: 2014-02-22
Online published: 2014-03-12
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21072071, 21272088).
Four novel indenyl phosphine gold complexes were prepared by the reaction of indenyl phosphine with AuCl-(SMe)2. All products 1～4 have been fully characterized by elemental analysis, spectroscopy, and X-ray crystal diffraction techniques for 2 and 4. Complex 2 has been found efficiently to catalyze hydration of alkyne with the advantages of mild reaction conditions, less catalyst, excellent atomic economy and environmental friendly.
Key words： indenyl; phosphine; gold; alkyne; hydration reaction
Han Zhijun , Mao Shulan , Peng Hui , Pi Yunxiao , Chen You , Liu Shenghua , Yu Guangao . Synthetic and Structural Studies on Indenyl Phosphine Gold Complexes and Application as Catalyst for Hydration of Alkynes[J]. Chinese Journal of Organic Chemistry, 2014 , 34(5) : 893 -897 . DOI: 10.6023/cjoc201401037
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