Chinese Journal of Organic Chemistry >
Preparation of Graphene/Poly(N,N-dimethylacrylamide) Nanocomposite via Cu-Catalyzed Single-Electron Transfer Living Radical Polymerization
Received date: 2014-04-28
Revised date: 2014-05-07
Online published: 2014-05-23
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 51073042, 51103026, 51373035, 51373040), the Shanghai Natural Science Funds (No. 11ZR1403100), the Shanghai Scientific and Technological Innovation Project (No. 11JC1400600), and the Shanghai Rising Star Program (No. 12QB1402900).
Exfoliated graphene oxide (GO) sheets were prepared from natural graphite by a modified Hummer's method, which included oxidative hydrolysis under strong acidic conditions and ultrasonic dispersing. GO was firstly reduced by hydrazine and then followed by a diazonium addition reaction to give graphene containing hydroxyls (G-OH), which was converted to graphene with singel eclectron transfer-living radical polymerization (SET-LRP) initiating groups via esterification with 2-chloropropionyl chloride. Finally, poly(N,N-dimethylacrylamide) (PDMAA) chains were grown from the surface of graphene via in situ SET-LRP to obtain graphene/PDMAA (G-PDMAA) nanocomposite. G-PDMAA nanocomposite showed good dispersity in common organic solvents and aqueous solution.
Wang Songyang , Guo Guannan , Yang Dong , Hu Jianhua . Preparation of Graphene/Poly(N,N-dimethylacrylamide) Nanocomposite via Cu-Catalyzed Single-Electron Transfer Living Radical Polymerization[J]. Chinese Journal of Organic Chemistry, 2014 , 34(7) : 1382 -1390 . DOI: 10.6023/cjoc201404052
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