Chinese Journal of Organic Chemistry >
A Novel Construction Method for (E)-3-Aryloxyacrylate Derivatives
Received date: 2014-05-01
Revised date: 2014-05-07
Online published: 2014-06-11
Supported by
Project supported by the Natural Science Foundation of Guangdong Province (No. S2012040007868) and the Excellent Young Scientist Fund of Guangdong Province Education Department (No.2013LYM_0059).
This paper reports a novel intermolecular addition and free radical homolytic reaction for the synthesis of (E)-3-aryloxyacrylate derivatives from alkynoates and phenols using N,N-dimethylformamide (DMF) as the solvent and CuO/CH3ONa as the system of promotion. The structures of product were confirmed by IR, 1H NMR, 13C NMR and elemental analysis. The results showed that this synthetic route had the advantages of easy-obtained raw materials, simple work-up and high purity product.
Key words： alkynoates; phenols; intermolecular addition; (E)-3-aryloxyacrylates
Chen Cui , Tan Liquan , Qiu Huihua . A Novel Construction Method for (E)-3-Aryloxyacrylate Derivatives[J]. Chinese Journal of Organic Chemistry, 2014 , 34(10) : 2152 -2155 . DOI: 10.6023/cjoc201405001
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