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Chinese Journal of Organic Chemistry >

2014 , Vol. 34 >Issue 7: 1347 - 1351

DOI: https://doi.org/10.6023/cjoc201406013

ARTICLE

Preparation of Polypyrrole/Anthraquinone-2-sulfonate Nanocomposite and Application in Li-Ion Battery

  • Zhang Chunming ,
  • Huang Zhao ,
  • Yang Yang ,
  • Wang Dan ,
  • He Dannong
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  • a National Engineering Research Center for Nanotechnology, Shanghai 200241;
    b School of Material Science and Engineering, Shanghai Jiaotong University, Shanghai 200240

Received date: 2014-06-10

  Revised date: 2014-06-14

  Online published: 2014-07-01

Supported by

Project supported by the National Natural Science Foundation of China (No. 21171116), the International Science & Technology Cooperation Program of China (No. 2012DFG11660), the Shanghai Natural Science Funds (No. 14ZR1429500), and the Shanghai Rising Star Program (No. 14QB1402900).

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Abstract

Anthraquinone-2-sulfonate (AQS) was prepared from phthalic anhydride by modified phthalic anhydride method and sulphonation method. Anthraquinone was synthesized by oxidation of sulfuric acid and phthalic anhydride. Then sulfonic acid group was introduced to the anthraquinone with fuming sulfuric acid to form AQS. And then polypyrrole (PPy)/AQS composite was synthesized by electrochemical in-situ polymerization reaction on current collector from the aqueous solution containing pyrrole and AQS. The prepared PPy/AQS composite material exhibited good charge/discharge property and cycling stability in the conventional organic electrolyte as organic electrode in lithium ion batteries.

Key words： polypyrrole; anthraquinone-2-sulfonate; Li-ion battery; cathode material

Cite this article

Zhang Chunming , Huang Zhao , Yang Yang , Wang Dan , He Dannong . Preparation of Polypyrrole/Anthraquinone-2-sulfonate Nanocomposite and Application in Li-Ion Battery[J]. Chinese Journal of Organic Chemistry, 2014 , 34(7) : 1347 -1351 . DOI: 10.6023/cjoc201406013

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