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Chinese Journal of Organic Chemistry >

2014 , Vol. 34 >Issue 11: 2224 - 2235

DOI: https://doi.org/10.6023/cjoc201405005

Benzimidazoles-Containing Transition Metal Complexes: A Novel Catalyst for Ethylene Oligomerization and Polymerization

  • Xiao Liwei ,
  • Li Lingling ,
  • Gao Hongjie ,
  • Ren Ping ,
  • Kou Wei ,
  • Shi Yaru
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  • Faculty of Chemistry and Material Science, Langfang Teachers University, Langfang 065000

Received date: 2014-05-05

  Revised date: 2014-06-06

  Online published: 2014-07-02

Supported by

Project supported by the Natural Science Foundation of Hebei Province (No.B2013408014) and the Key Foundation of Langfang Teachers University (No.LSZZ201302).

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Abstract

Benzimidazole heterocycles have good selectivity for coordination and can form a variety of metal complexes, which exhibit excellent biological, fluorescence and catalytic properties. In this paper, the progress for synthesis of benzimidazoles-containing transition metal complexes and their catalytic activity for ethylene oligomerization and polymerization are summarized, and the influence of the structural factor of complexes such as electronic effect and steric effect of substituent group on the catalytic performance is discussed.

Key words： benzimidazole; coordination catalysis; ethylene oligomerization and polymerization; structure-activity relationship

Cite this article

Xiao Liwei , Li Lingling , Gao Hongjie , Ren Ping , Kou Wei , Shi Yaru . Benzimidazoles-Containing Transition Metal Complexes: A Novel Catalyst for Ethylene Oligomerization and Polymerization[J]. Chinese Journal of Organic Chemistry, 2014 , 34(11) : 2224 -2235 . DOI: 10.6023/cjoc201405005

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