Chinese Journal of Organic Chemistry >
Recent Progress on Cu-Catalyzed Asymmetric Conjugate Borylation to α,β-Unsaturated Compounds
Received date: 2014-09-09
Revised date: 2014-09-30
Online published: 2014-10-09
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21372243, 21102161).
Organoborons are an important class of organic compounds, because organoboronic acids and their derivatives can be readily converted into a wide variety of functionalities in a stereospecific manner. Cu-catalyzed asymmetric conjugate borylation of unsaturated compounds with bis(pinacolato)diboron (B2pin2) has emerged as a novel synthetic tool to afford a variety of organoboron compounds. Herein, this research progress, which involves using bisphosphine, N-heterocyclic carbine, and other chiral ligands, is summarized.
Liu Qiang , Tian Bing , Tian Ping , Tong Xiaofeng , Lin Guo-Qiang . Recent Progress on Cu-Catalyzed Asymmetric Conjugate Borylation to α,β-Unsaturated Compounds[J]. Chinese Journal of Organic Chemistry, 2015 , 35(1) : 1 -14 . DOI: 10.6023/cjoc201409019
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