Chinese Journal of Organic Chemistry >
Nanoparticles Pd-Catalyzed Suzuki and Heck Cross-Coupling Reactions of Arenediazonium Tetrafluoroborate Salts
Received date: 2014-07-12
Revised date: 2014-09-11
Online published: 2014-10-23
Supported by
Project supported by the Natural Science Foundation of Shanxi Province (Nos. 2012021007-2, 2011011010-2) and the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (No. 20120006)..
An efficient protocol for the Suzuki and Heck reactions of arenediazonium tetrafluoroborate salts catalyzed by Pd(PPh3)4-derived nanoparticles palladium catalyst has been developed. This method is able to prepare a variety of biaryls and aryl olefin under air atmosphere at 25 ℃ in ethanol. In the presence of this catalyst, the cross-coupling reactions of arenediazonium tetrafluoroborate salts with arylboronic acids and olefin proceed smoothly and afford the desired coupling products with good yields, respectively. The catalyst could be recycled 4 times without loss of activity and decrease of yield.
Key words： nanoparticle palladium; Suzuki; Heck; Pd/Al2O3; biphenyls; aryl olefin
Zhao Xiaoxia , Chang Honghong , Li Xing , Wei Wenlong . Nanoparticles Pd-Catalyzed Suzuki and Heck Cross-Coupling Reactions of Arenediazonium Tetrafluoroborate Salts[J]. Chinese Journal of Organic Chemistry, 2015 , 35(2) : 478 -483 . DOI: 10.6023/cjoc201407023
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