Chinese Journal of Organic Chemistry >
Phosphonium Ionic Liquids-Accelerated Morita-Baylis-Hillman Reaction
Received date: 2014-10-14
Revised date: 2014-11-16
Online published: 2014-12-08
Supported by
Project supported by the Key Discipline Project of Shanxi Province Education Department (No. 20141010), the Graduates Innovation Project of Shanxi Province (No. 020352901016) and the Key Discipline Project of Xinzhou Teachers University (No. XK201304).
Phosphonium ionic liquids, due to their superior thermal stability and an inertness in weak basic reaction media, are receiving more and more attention. A series of phosphonium ionic liquids have been prepared starting from cheap tributylphosphine with various halogenated hydrocarbon. Then using 1,4-diazabicyclo[2.2.2]octane (DABCO) as catalyst and water-phosphonium ionic liquid composite system as reaction media, Morita-Baylis-Hillman reactions of a variety of aldehydes with acrylonitrile, methyl acrylate or acrylamide were studied. Experimental results showed that the composite system of phosphonium ionic liquid with water can effectivily accelerate the Morita-Baylis-Hillman reactions of aromatic aldehydes and aliphatic aldehydes, and fast reaction rate and high yield were obtained.
Zhao Sanhu , Wang Dou , Wang Min , Kang Jin , Zhang Liwei . Phosphonium Ionic Liquids-Accelerated Morita-Baylis-Hillman Reaction[J]. Chinese Journal of Organic Chemistry, 2015 , 35(4) : 865 -874 . DOI: 10.6023/cjoc201410020
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