Chinese Journal of Organic Chemistry >
Synthesis of 1'-Arylmethyl-1-(1,2-dienyl)ferrocenes
Received date: 2015-02-08
Revised date: 2015-03-08
Online published: 2015-03-13
Supported by
Project supported by the National Natural Science Foundation of China (No. 21262023) and the Natural Science Foundation of Inner Mongolia of China (No. 2014JQ02).
A convenient procedure for synthesizing 1'-arylmethyl-1-(1,2-dienyl)ferrocene derivatives was explored. Using commercially available ferrocene as the starting material, the six target compounds were obtained in five steps via Friedel-Crafts acylation, reduction, acetylation, acetylene formation and modified Crabbé reaction. The structures of the obtained allenes were characterized by 1H NMR and 13C NMR and HRMS.
Key words： ferrocene; allene; 1'-arylmethyl-1-(1,2-dienyl)ferrocene; synthesis
Wang Chenjun , Wang Han , Ma Chao , Zhang Kaixin , Han Fei , Li Baoguo , Chen Shufeng . Synthesis of 1'-Arylmethyl-1-(1,2-dienyl)ferrocenes[J]. Chinese Journal of Organic Chemistry, 2015 , 35(7) : 1544 -1550 . DOI: 10.6023/cjoc201502013
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