Chinese Journal of Organic Chemistry >
Synthesis of 1,2,3,4,5-Pentaarylcyclopenta-2,4-diene Derivatives and Their Aggregation-Induced Emission Properties
Received date: 2015-02-26
Revised date: 2015-03-30
Online published: 2015-04-03
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 91333113, 21303060), the National Basic Research Program of China (973 Program, No. 2014CB643502), the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB12010200), and the Guangdong Natural Science Foundation (No. S2013010014418).
Pentaarylated cyclopentcyclodienes have aggregation-induced emission (AIE) characteristics and can be easily derivatized, but are rarely studied. In order to examine the effect of the electronic properties and the position of the substituents on AIE properties, an expedient method for the synthesis of a series of pentaarylated cyclopentadiene derivatives was developed, and their UV-Vis, fluorescence spectra, fluorescence quantum yields as well as the XRD structures of single crystals were investigated. The AIE properties of pentaarylated cyclopentadiene derivatives were studied in detail.
Qiu Shuhai , Xu Shengjie , Zhou Guofu , Shui Lingling , Zhu Xiaozhang . Synthesis of 1,2,3,4,5-Pentaarylcyclopenta-2,4-diene Derivatives and Their Aggregation-Induced Emission Properties[J]. Chinese Journal of Organic Chemistry, 2015 , 35(8) : 1746 -1753 . DOI: 10.6023/cjoc201502031
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