Chinese Journal of Organic Chemistry >
Synthesis, Special Recognition to Cu2+ and Cr3+ of the Ferrocenyl Derivatives
Received date: 2015-01-14
Revised date: 2015-03-25
Online published: 2015-05-08
Supported by
Project supported by the National Natural Science Foundation of China (No. 21002024) and the Educational Commission of Hubei Province of China (No. D20131007).
A series of ferrocenyl derivatives FeL1~FeL4 were synthesized by ferrocenyl aldehyde, 1,1'-ferrocene-dicarbox-aldehyde, 2,6-diaminepyridine and 2-amine-7-methyl-1,8-naphthyridine. Their structures were characterized by NMR, MS and element analysis. Cyclic voltammetry (CV) was carried out to observe their electrochemical properties. The interactions between FeL1~FeL4 and metal ions were investigated by UV-Vis and NMR titration. The results indicated that the derivatives FeL1 and FeL2 showed a very good special recognition to Cu2+ and Cr3+, and the derivatives FeL3 and FeL4 showed an excellent special recognition only to Cr3+ in the mixed solution contained fifteen kinds of metal ions. Thus, this method has potential applications in the monitoring of vitro environmental pollution and in the detection of vivo metal ions, which exceed the standard.
Huang Min , Lou Zhaowen , Peng Xiaoqian , He Hanping , Zhang Xiuhua , Wang Shengfu . Synthesis, Special Recognition to Cu2+ and Cr3+ of the Ferrocenyl Derivatives[J]. Chinese Journal of Organic Chemistry, 2015 , 35(9) : 1966 -1974 . DOI: 10.6023/cjoc201501014
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