Chinese Journal of Organic Chemistry >
L-Tyrosine-Grafted Graphene Copper for Catalyzing N-Arylation of Nitrogen Heterocycles
Received date: 2015-04-19
Revised date: 2015-06-18
Online published: 2015-07-10
Supported by
Project supported by the National Natural Science Foundation of China (No. 21303139).
The catalytic performance of L-tyrosine-grafted graphene copper (Tyr-G-Cu) was investigated in the N-arylation of nitrogen heterocycles. In the presence of this catalyst, the N-arylation proceeded smoothly and afforded the desired coupling products with good yields, respectively. Meanwhile, the catalyst was reused five times without remarkable loss of activity. Finally, the plausible heterogeneous recycle process of catalyst was identified by typical hot filtration test.
Key words： L-tyrosine; graphene; copper catalysts; N-arylation; heterogeneous catalysis
Zhou Limei , Lang Wencheng , Jiang Xiaohui , Huang Qiang , Yin Mengyun . L-Tyrosine-Grafted Graphene Copper for Catalyzing N-Arylation of Nitrogen Heterocycles[J]. Chinese Journal of Organic Chemistry, 2015 , 35(11) : 2340 -2346 . DOI: 10.6023/cjoc201504028
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