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Chinese Journal of Organic Chemistry >

2015 , Vol. 35 >Issue 12: 2552 - 2558

DOI: https://doi.org/10.6023/cjoc201506024

Articles

PhI(OAc)2/I2-Mediated Oxidative Homocoupling of N-Alkoxyamides: An Approach to Esters

  • Duan Xiyan ,
  • Duan Xibin ,
  • Yang Kun ,
  • Wang Zhicheng ,
  • Zhang Lua ,
  • Tong Yue ,
  • Liu Haozhe ,
  • Du Ke ,
  • Tang Rongze
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  • a School of Chemical Engineering & Pharmaceutics, Henan University of Science and Technology, Luoyang 471023;
    b Zhengzhou Certral Hospital Affiliated to Zhengzhou University, Zhengzhou 450007

Received date: 2015-06-18

  Revised date: 2015-07-24

  Online published: 2015-08-26

Supported by

Project supported by the Students Research Training Program of Henan University of Science and Technology (No. 4008-13480042).

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Abstract

A variety of substituted N-alkoxyamides derivatives were found to be converted to the corresponding esters mediated by PhI(OAc)2/I2. This novel strategy allows for an efficient synthesis of esters and is highlighted by appealing features such as readily available of the starting material, mild reaction condition, wide substrate scope and transition-metal-free characteristics.

Key words： hypervalent iodine; N-alkoxyamides; ester; oxidative coupling

Cite this article

Duan Xiyan , Duan Xibin , Yang Kun , Wang Zhicheng , Zhang Lua , Tong Yue , Liu Haozhe , Du Ke , Tang Rongze . PhI(OAc)2/I2-Mediated Oxidative Homocoupling of N-Alkoxyamides: An Approach to Esters[J]. Chinese Journal of Organic Chemistry, 2015 , 35(12) : 2552 -2558 . DOI: 10.6023/cjoc201506024

References

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