Chinese Journal of Organic Chemistry >
Reaction Mechanisms of Carbonyl Compounds Hydrosilylation Catalyzed by Group VIII Transition Metal Complexes
Received date: 2015-07-29
Revised date: 2015-09-21
Online published: 2015-09-30
Supported by
Project supported by the National Natural Science Foundation of China (No. 21203115) and the Shanxi Scholarship Council of China (No. 2012-057)
Hydrosilylation is an important reaction widely used in the silicone industries. Especially, the hydrosilylation of carbonyl compounds is of great value in synthetic organic chemistry. A variety of transition-metal complexes, such as iron, palladium, rhodium, ruthenium, platinum, etc., are now known to show catalytic activity in the hydrosilylation of ketones. Since organohydrosilanes may involve one, two, or three Si—H bonds in tertiary, secondary or primary silanes, respectively. The various types of compounds were produced in their reactions with the unsaturated substrates catalyzed by transition-metal complexes. In this paper, several reaction mechanisms of carbonyl compounds hydrosilylation catalyzed by group VIII transition metal complexes under different reaction conditions are mainly introduced. In particular, the new developments on mechanistic pathways for Rh, Ru, Fe and Ir catalytic systems from the type of reaction mechanism and the influence of reaction conditions are highlighted. In addition, some key intermediates and transition states, and their energetics are presented. Not only a summary of previous work is given, but also some ideas and inspirations are provided for future research.
Qin Xiaofei , Liu Xiaoyan , Guo Caihong , Wu Haishun . Reaction Mechanisms of Carbonyl Compounds Hydrosilylation Catalyzed by Group VIII Transition Metal Complexes[J]. Chinese Journal of Organic Chemistry, 2016 , 36(1) : 60 -71 . DOI: 10.6023/cjoc201507037
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